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Study On The Influence Factors of The Treatment of The Oily Wastewater Experiments by Orthogonal Experiment
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CHEN Bin, CHEN Zhe, AN Ning
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 1-3.
doi:10.16039/j.cnki.cn22-1249.2020.09001
The factors affecting the treatment of oily wastewater with the compound flocculant polyferric sulfate and chitosan were studied by orthogonal experiment.In the experiment, light transmittance, oil content and suspended matter content were selected as test indexes.By means of range analysis of orthogonal experimental results, the order of influence factors such as temperature, PH value, compounding ratio and dosage of flocculant on each index was obtained.After comprehensive analysis, the optimal level combination of each factor was obtained as temperature 50℃, pH 7, inorganic/organic 3:1 and dosage 40mg/L.
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Discussion on the Reform of Natural Gas Energy Measurement
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SUN Xiangtai
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 4-8.
doi:10.16039/j.cnki.cn22-1249.2020.09002
Natural gas measurement is divided into volume measurement, quality measurement and energy measurement.At present, China's domestic natural gas trade transfer mainly adopts volume measurement.With the establishment of the national pipeline network company, the interconnection of China's natural gas pipeline network will be accelerated.In order to ensure the fair and just transfer of natural gas trade measurement between different interfaces, natural gas energy measurement will be imperative.This paper analyzes the problems faced by natural gas energy measurement, studies and analyzes the metering interface, measurement error, pricing standard, reform resistance and other aspects, and puts forward specific solutions and suggestions, so as to promote the comprehensive implementation of energy measurement reform of natural gas in China.
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The Effect of F Substituent on the Electron Structures and Spectroscopic Properties of Transition Metal Iridium Complexes
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NIE Jianhang, WANG Zixuan, WANG Tianqi, ZHANG Jianpo
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 18-22.
doi:10.16039/j.cnki.cn22-1249.2020.09005
The structures and spectroscopic properties of a series of (C^N)2Ir(idpt) [C^N= 2-phenylpyridine(1), 2-(5-fluorophenyl)pyridine(2), 2-(4,5,6-trifluorophenyl)pyridine(3), idpt= imidodiphosphinate] complexes were investigated by the density functional methods. We first optimized geometrical structure in ground state of complexes 1-3, at the B3LYP/LanL2DZ levels, and the excited state structures by selected UB3LYP/LanL2DZ functional. The calculated bond lengths of Ir-N(1), Ir-C(1), and Ir-O(1) in the ground state agree well with the corresponding experimental results. At the TD-DFT and CPCM levels, 1-3 give rise to lower energy absorptions at 447(1), 452(2), 424(3) nm and corresponding phosphorescent emissions at 541(1), 499(2), 466(3) nm, respectively. The HOMOs of 1-3 are mainly localized on the metal and bidentate ligands, while the LUMOs are the π* type orbital of bidentate ligands. Therefore, the transition of 1-3 were assigned to the metal-to-ligand and ligand-to-ligand charge transfer (MLCT/LLCT) transition. It is shown that the emitting color are significantly dominated by the phenylpyridine ligand itself and F-substituent group.
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Optimization Design of Battery Pack Enclosure Based on Optistruct
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TAN Lihui, LI Chunyang
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 34-39.
doi:10.16039/j.cnki.cn22-1249.2020.09008
In this paper ANSYS Workbench platform is used for static and dynamic finite element analysis of the battery pack enclosure, and the weak position of the box structure is obtained. The box is Optimized by the topography and composite material optimization, The optimum geometric parameters and plane layout of the convex hull on the box cover are obtained by topography of the Optistruct software, final the three-dimensional model of the optimized upper cover is established. The thickness distribution and optimal thickness of each layer in the lower box is obtained by the composite material optimization. After verification, the maximum deformation of the box after optimization is 82% lower than that before optimization, the stiffness is significantly increased, the maximum equivalent stress is reduced by 70%, and the box strength is significantly improved. The first-order natural frequency is 32.5Hz, which can avoid resonance, the box weight is reduced by 67. After optimization the battery pack box can play more effective protective role for the safe operation of the power battery, and the weight reduction effect is significant, the research lays the foundation for further analysis of the actual battery box structure.
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Design of Inversion Controller for Ball-and-Plate System with Low-pass filter
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MENG Shengjun, HAN Guangxin
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 40-45.
doi:10.16039/j.cnki.cn22-1249.2020.09009
For the problem of the nonlinearity,uncertainty and external disturbance of the ball and plate system,in order to make the ball trajectory tracking of the desired dynamic quality,according to the Lyapunov stability theory,firstly combine the state space model of ball and plate system with the low-pass filter,then define the system deviation,select the appropriate Lyapunov function and obtain the virtual function,and finally gradually deduce an inversion controller with low-pass filter.The simulation results show that the improved controller can effectively filter the interference of the system itself and the outside,improve the control precision,and meet the control requirements of the system.
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Determination and Analysis of 19 Elements in Jujube by ICP-MS Method
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WANG Zhaoguo, YU Zheyuan, WANG Ji
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 70-76.
doi:10.16039/j.cnki.cn22-1249.2020.09016
A single-mode microwave digestion-inductively coupled plasma mass spectrometry (ICP-MS) method was established for the simultaneous determination of 19 elements in Jujube. The sample was processed with a full-automatic single-mode microwave digestion-digesting instrument. The ICP-MS analysis conditions were selected and optimized and tested by computer. The results showed that the standard curve concentration of Ag, As, Cr, Ni and other 12 elements ranged from 0 to 50 ng/mL, and the correlation coefficients were all greater than 0.995, showing a good linear relationship. The standard curve concentrations of Al, Ba, Cu, Fe and other 7 elements ranged from 0 to 1000 ng/mL, and the correlation coefficients were all greater than 0.995, showing a good linear relationship. The standard recovery test of each concentration gradient element was conducted at the three levels of 1-fold low-limit, 2-fold low-limit and 10-fold low-limit, and the standard recovery was between 65% and 110%, which met the requirements of quantitative analysis of trace elements. The test method in this study is simple, convenient, reliable, and has high precision and accuracy, which can meet the daily detection requirements of multiple elements in Jujube, and provide technical support for its quality control and safety evaluation.
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BSA Detection Using AuNCs@GSH-CAP Fluorescence Enhancement System
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CHENG Kaixuan, YIN Jianhang, XU Na
Journal of Jilin Institute of Chemical Technology, 2020, 37(9): 81-84.
doi:10.16039/j.cnki.cn22-1249.2020.09018
Protein research is a hot spot at present, and has been involved in biology, medicine, food and other fields, and the development of nanotechnology has greatly promoted the research on protein. Simple, highly sensitive and highly selective detection is the key to the early diagnosis and treatment of major diseases, and it is also the direction with great market potential. However, the synthesis of fluorescent probes for many detection methods is complex and costly, and requires the use of toxic organic reagents. In this study, we detected bovine serum albumin (BSA) using a gold nanocluster (AuNCs@GSH) system with fluorescence quenching by chloramphenicol (CAP) as a probe. BSA could enhance the fluorescence intensity of AUNCs-GSH-CAP system, which was positively correlated with the concentration of BSA within a certain concentration range. This method has good selectivity and anti-interference, and the fluorescence effect is obvious. It has achieved a good linear relationship within 10-160 mol/L, and its detection limit is 0.1 mol/L, which has a good prospect for the rapid detection of proteins.
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