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The Synthesis and Electrochemical Properties of NiCo2O4 Arrays on Nickel Foam
Collect
LV Yang, ZHANG Yuewei, YU Xue
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 1-4.
doi:10.16039/j.cnki.cn22-1249.2019.11.001
NiCo2O4 arrays with two different morphologies were synthesized on nickel foam through a hydrothermal method followed by a calcination process. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) experiments were carried out to them respectively. Results show that the samples are pure NiCo2O4, cover fully on the surface of Ni foam and morphologies uniformity. Moreover, the electrochemical measurements indicate: the sample synthesized with hydrothermal solution ratio of alcohol to water is 1:6, exhibited an areal specific capacitance as high as 1.57 F/cm2 at a current density of 3 mA/cm2; the sample synthesized with hydrothermal solution ratio of alcohol to water is 3:4, exhibited an areal specific capacitance as high as 1.28 F/ cm2 at a current density of 3 mA/cm2. Furthermore, the sample synthesized in this paper shows robust rate capability.
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Synthesis and Process Optimization of New Antioxidant 3426
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GUO Junlin, TONG Xiwang, Wang Meng, YU Liying, NING Bo
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 5-8.
doi:10.16039/j.cnki.cn22-1249.2019.11.002
This article discussed with 2, 2 '- methylene double (4 - methyl - 6 - tertiary butyl phenol) referred to as the antioxidants, (antioxidant 2246) reaction, propionyl chloride as raw materials, triethylamine as the bound acid agent, using dichloromethane as solvent, the direct synthesis of 2 - (2 - hydroxy - 3 - tert-butyl - 5 - methyl benzyl) - 4 - methyl - 6 - tert-butyl phenyl propionate (hereinafter referred to as antioxidant 3426) method.The effects of molar ratio n(antioxidant 2246):n(propionyl chloride), reaction time and reaction temperature on the yield were studied.The synthesis method is green and the solvent can be recycled, in line with the concept of green chemistry.
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Synthesis of Furoin Catalyzed by VB1
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CHENG Leqin, YU Xue
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 9-11.
doi:10.16039/j.cnki.cn22-1249.2019.11.003
Furoin was synthesized by benzoin condensation reaction using furaldehyde as raw material, VB1 as catalyst and Na2CO3 as basic reagent. The effects of solvent ratio, amount of VB1 and alkali, reaction temperature and time were discussed, and the structure of condensation product was confirmed by melting point determination and IR spectroscopy. The experimental results show that the optimal condition was furaldehyde (10 mL, 0.12 mol), 95% ethanol (20 mL), VB1 (1.80 g), 10% Na2CO3 (8.0 mL), at 60 oC for 1.0 h, the best yield was upto 84.56%.
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Hydrodynamic Load Analysis and Experimental Study of Grouting Clamp under Wave and Ocean Current
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WANG Kun, WANG Zhuo, WANG Yijian
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 25-32.
doi:10.16039/j.cnki.cn22-1249.2019.11.007
The repair of the offshore platform jacket is an important research direction of ocean engineering, and the grouting clamp reinforcement and repair is the most widely used. In order to solve the hydrodynamic interference problem of grouting clamp under the combined action of wave and current in complex sea conditions, this paper uses Morison formula to analyze the linear wave load on the grouting clamp. Determine the wave force and sea flow force of the vertical and horizontal grouting clamps, and calculate the hydrodynamic load. When the grouting clamp is in the vertical state, the maximum wave load is 23341N and the maximum sea current is 8062.65N. Finally, using the press to carry out the anti-offload test of the clamp, it is verified that the slippage force of the grouting clamp is far greater than the wave load force received. The innovation can be summarized as a hydrodynamic comprehensive analysis of the grouting clamps in the vertical and horizontal directions. The feasibility of implementing the grouting clamp reinforcement method in the local damage repair operation of the offshore platform jacket was confirmed.
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Experimental Performance Analysis of Negative Pressure Adsorption Dustless Blackboard Eraser
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XIE Xiaoyu, WANG Lei, Wei Yabo, Hou Xiaohu, Shi Liangcai
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 39-42.
doi:10.16039/j.cnki.cn22-1249.2019.11.009
Aiming at the problems of traditional blackboard eraser, such as fugitive dust, incomplete wipe and poor use effect, etc. The article designed a negative pressure adsorption dustless blackboard eraser. The blackboard eraser is separated by a coarse filter net, with a compressed cavity inside. The negative pressure generated by fan drainage is used to absorb the dust generated by cleaning in real time. Through fluid simulation analysis and experimental test, the dust absorption rate can be more than 90%. At the same time, the blackboard eraser adopts wireless automatic charging, which has super-long standby performance.
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Water Quality Assessment of Typical Urban Lakes in Songhua River Basin
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GU Feng, WU Chunying, BAI Lu
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 53-57.
doi:10.16039/j.cnki.cn22-1249.2019.11.013
Analyzed the water quality in Lake Luoma, the results indicate that its major contaminants are TN (total nitrogen), TP (total phosphorus) and volatile phenol. Based on the parameters of Chemical Oxygen Demand, Dissolved Oxygen and Chlorophyll a, the comprehensive trophic state index method are applied for assessing the eutrophication of Lake Luoma, and the results confirm that its water quality is heavy eutrophic. The water quality of Lake Luoma meets the level of Ⅳ to Ⅴ classification of surface water environmental quality standards. The nitrogen in the lake is sufficient, and the growth of algae is controlled by the phosphorus. Water eutrophication of the lake is phosphorus-controlled.
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Study on Optimization Process of Propylene Polymerization Initiated by Ziegler-Natta Catalyst System
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Song Yan, Zhou Linyuan, Wang Fangfei, Liu Chuang
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 58-62.
doi:10.16039/j.cnki.cn22-1249.2019.11.014
One-step preparation process using anhydrous magnesium chloride as carrier.The effects of ester-magnesium ratio, alcohol magnesium ratio, magnesium precursor composition, stirring and heating rate on Ziegler-Natta catalyst activity, polypropylene (PP) bulk density and isotacticity were investigated.The surface structure of the catalyst was investigated. The Ziegler-Natta catalyst system was optimized.The results showed that the comprehensive performance of Polypropylene was the best when the ratio of ester to magnesium was 0.255, the ratio of alcohol to magnesium was 2.6, the proper amount of ethoxy magnesium was added to the precursor,and the heating time was 4 h.
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Preparation of Carboxymethylcellulose / Graphene Oxide Composite Electrochemical Biosensor and Its Detection Performance for Vitamin B6
Collect
Cui Meng, Xin Yuhang, Song Rui, Sun Qiyuan, Gao Di
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 63-70.
doi:10.16039/j.cnki.cn22-1249.2019.11.015
The method and technology of sensing, analyzing and detecting the biological macromolecules and drugs by biosensors is an important subject in biomedicine and materials science. The design and development of sensitive and easy-to-operate detection materials for biological macromolecules and drug molecules is a hotspot in this field in recent years. Due to the limitation of its structure or performance, it is difficult to meet the detection requirements by using a single material. It is a key basic subject to design and construct a material system with special structure by compounding two or more materials to obtain a composite drug detection system with excellent comprehensive performance. In this study, an intelligent biosensor based on carboxymethyl cellulose (CMC) and graphene oxide was investigated. The detection limit, detection range, selectivity and stability of the composite smart biosensor for vitamin B6 were studied. The excellent performance of CMC as matrix material of biosensor was revealed.
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Structure and Electrical Conductivity of GDC Doped with Li2CO3,SrCO3 Electrolyte in Solid Oxide Fuel Cell
Collect
SUN Cuicui, MENG Xiangwei, LV Shiquan, ZHANG Yanlei, WANG Lizhong, CHAI Yuan
Journal of Jilin Institute of Chemical Technology, 2019, 36(11): 86-89.
doi:10.16039/j.cnki.cn22-1249.2019.11.020
Composite electrolytes were prepared by doping carbonates (Li2CO3 53 mol% and SrCO3 47mol%) with different mass fractions (10%, 20%, 30%) into electrolyte (GDC). The electrochemical properties of the composite electrolyte were characterized by conductivity test and scanning electron microscopy (SEM). Anode powder was prepared by doping composite electrolytes into NiO, and the cathode powder was obtained by compounding the composite electrolytes with Li-treated NiO.The anode, cathode and electrolyte prepared above were pressed by dry pressure method to obtain a single cell supported by the anode. The performance of the cell was characterized later. The results of electrochemical performance of single cell show that GDC with 20% carbonate has the highest power density, which is 100mW/cm2 at 650℃.
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