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       Volume 35 Issue 7, 25 July 2018 Previous Issue  
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    Development of Industrial Robots and Construction Thoughts of  Integrated Training System in Local Engineering College   Collect
    Qu Yongyin, Ai Xuezhong, Gao Xingquan, Liu Qi
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 1-7.   doi:10.16039/j.cnki.cn22-1249.2018.07.001
    Abstract     PDF(3341KB)
    On the basis of briefly summarizing the development of robots at home and abroad,the construction thought of integrated traning system for industrial robot is  proposed. From the perspective of local engineering, it contains the integration of basic theories and basic experiments, and that of comprehensive theory and engineering education as well as that of cross theory and innovation practice. And the measures are also discussed to speed up the education of industrial robots.
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    Advances in identifications of valence-variable rare-earth ions in BaTiO3 ceramics and in defect chemistry   Collect
    Lu Da-yong
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 8-13.   doi:10.16039/j.cnki.cn22-1249.2018.07.002
    Abstract     PDF(564KB)
    In the field of dielectric materials, this paper reviews the research advances in the identifications on valence states and site occupations of four kinds of valence-variable rare-earth ions (Ce, Pr, Eu, and Tb) in BaTiO3 ceramics for a decade in Research Center for Materials Science and Engineering (RCMSE), Jilin Institute of Chemical Technology. Some research findings are introduced briefly for the applications of these valence-variable rare-earth ions in double rare-earth-doped BaTiO3 ceramics (DRBT). 
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    Hardware-in-the-loop Simulation Platform for Coupled-tank Control System Based on Quanser data Acquisition Card   Collect
    GAO Xingquan, WANG Zishuo, ZHU Qiang, ZHAO Qiang
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 14-17.   doi:10.16039/j.cnki.cn22-1249.2018.07.003
    Abstract     PDF(1531KB)
    A hardware-in-the-loop simulation platform for coupled-tank control system based on Quanser data acquisition card and SIMULINK software are designed. First, its hardware structure and implement scheme of key technique are introduced in this paper. Then, controller realization and its parameter tuning process are illustrated by the example of PI controller. The experimental results show that the characteristic of controller can be verified well and the development cycle of control system can be shortened largely using the designed platform .
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    Study on activity and sedimentary performance of microorganism by pressurized aeration   Collect
    Chen libo, Yan guangping
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 18-20.   doi:10.16039/j.cnki.cn22-1249.2018.07.004
    Abstract     PDF(1378KB)
    In this paper, the activity and sedimentary performance of microorganism of pressurized aeration bio-reactor are studied. The research show: when pressure increases 0.1 MPa , the activity of microorganism will be doubled. When pressure is 0.25MPa,SVI of microorganism is between 75~110 , larger and dense zoogloea are cultivated. The activity and sedimentary performance of microorganism are improved by increasing aeration pressure.
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    Identification and degradation effect of two oil degrading bacteria screened from oily wastewater   Collect
    LIU Hong, GAO Peng fei, CONG Weiyi, Wang Mingchao, Wen Gang, Tian Zhen
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 21-25.   doi:10.16039/j.cnki.cn22-1249.2018.07.005
    Abstract     PDF(517KB)
    Two strains screened from oil wastewanter were identified using 9 physiological and biochemical tests,16s rDNA technology and degradation effect of petroleum hydrocarbons components by two single strain were studied. Results showed that the two strains were:L2-Ochrobactrum ciceri sp.and L3-Serratia marcescens sp. The effect of 2 strains of single bacteria on petroleum hydrocarbon degradation was very efficient,It revealed that petroleum hydrocarbons degradation rate of L4 was up to 97.37% and 98.98% after incubated in a rotary shaker at 30℃ and 120 r/min for 6 days and initial concentration of petroleum hydrocarbons was 4000 mg/L. Two kinds of bacteria on the first 3 days of the oil degradation rate was faster, and then enter the stationary phase, the growth rate was slow until zero.
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    Study on the modification of isobutylated products of P - methylphenol dicyclopentadiene   Collect
    Gao Yuting, Dai Chuanbo
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 26-28.   doi:10.16039/j.cnki.cn22-1249.2018.07.006
    Abstract     PDF(458KB)
    A new method of modification of polyphenol antioxidant was explored. CPL esterification was synthesized by esterification with acrylic acid, phosphorus oxychloride and triethylamine. A single factor experiment was carried.The optimum process conditions are as follows: m (polyphenol compound): m (acrylic acid): m (phosphorus oxychloride): m (triethylamine) =18:2:4:3, the optimum reaction temperature is 79℃, and the heat preservation reaction time is 2.5h. Under this technological condition, esterification. The esterification rate 88 to 90%.
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    Drying Mechanism and Development Status of Centrifugal Dryer   Collect
    DUAN Shiming, ZENG Xinfang, CHEN Qing
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 29-34.   doi:10.16039/j.cnki.cn22-1249.2018.07.007
    Abstract     PDF(4078KB)
    The mechanism,evolution of centrifugal pellet dryer and the wide application in drying pellet in granulation for petrochemical and food processing are reviewed. One typical dryer structures,the Gala model is reviewed. However,the research of quantitative relations of output and drying index with structure size and operational variables is inadequacy. The effects of particle characteristics (such as material, shape, surface structure) on dry effect, output and noise are not quantitatively studied. The structural study of the rotor is limited to laboratory-level equipment. Thus,theoretical research is urgent for choosing appropriate type and size of dryer and developing more effective and highly productive  machines for wider engineering use.
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    Fluorescence Method for Determination of Mercury(II) Ions Based on DNA and Monolayer Tungsten disulfide   Collect
    Yanan Guan, Hao Zhang, Xiaoshuang Li, Lili Lian, Xiyue Wang, Wenxiu Gao, Bo Zhu, Dawei Lou
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 36-38.   doi:10.16039/j.cnki.cn22-1249.2018.07.008
    Abstract     PDF(456KB)
    Fluorescence was used to detect mercury (II) ions (Hg2+). The feasibility of this method was discussed and the effect of tungsten disulfide (WS2) concentration on the experiment was studied. Different concentrations of Hg2+ ions were detected, followed by their selectivity, and whether other metal ions interfered with the detection of Hg2+ ions. The experimental results show that this method has the advantages of simple operation, low cost and good selectivity.
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    Hygienic research of the Maydis stigma oral liquid with anti-fatigue effects   Collect
    TIAN Hai-ping, CUI Hao, LI Bing, ZHOU Hong-li
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 39-43.   doi:10.16039/j.cnki.cn22-1249.2018.07.009
    Abstract     PDF(4987KB)
    Objective: To study the hygienic performance of the Maydis stigma oral liquid with anti-fatigue effects in different periods. Method: Place on the 0 month, 6 months and 36 months of Maydis stigma oral liquid, the solution of Staphylococcus aureus and Salmonella was examined, respectively. Results: Staphylococcus aureus and Salmonella were not detected at different periods, but gram-negative bacilli was detected in the final test of blood plate. Conclusion: The test resultsof microbial limit from the Maydis stigma oral liquid meet the requirment of the GB 4789-2016.
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    Research profile of  the  extraction,purification and determination of flavonoids  in plants   Collect
    WANG Hong-biao, WANG Peng-hui, QIN Jia-ju, ZHOU Hong-li
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 44-47.   doi:10.16039/j.cnki.cn22-1249.2018.07.010
    Abstract     PDF(323KB)
    Abstract:This paper reviews the on the  extraction,purification technology and content determination of flavonoids in plants.It isgoing to be provide guidance for the future research and development of flavonoids.
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    Study on the Isolation of Protopanaxatriol Type Saponins based on D101C Macroporous Adsorption Resin   Collect
    Cheng Le-qin, Zhang Yue-wei, Li Yan-chun, Li Ling, Sun Shuo
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 48-52.   doi:10.16039/j.cnki.cn22-1249.2018.07.011
    Abstract     PDF(480KB)
    Protopanaxatriol group (PPT) is one of the two major tetracyclic triterpenoid saponins, responsible for anti-fatigue, anti-stress effects. This report studied the influence on adsorption of total PPT and PPD on D101C macroporous resin, by factors including concentration of total ginsenosides in stem and leaf, temperature and time of adsorption. In addition, influence of ethanol percentage was evaluated for desorption. Experimental results demonstrates that D101C microporous adsorption resin can adsorb 15 mg/mL of total ginsenosides at 15 ℃ after 14 hours, with PPT content further elevated to 86.8% from 27.2% and increased ratio of PPT to PPD (185:1 from 1.1:1) by desorption of 45% ethanol at 25 ℃ for 14 hours, indicating a better extraction and purification method of isolation and purification.
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    Microwave synthesis of imidazole ionic liquids containing biphenyl group   Collect
    Yunxia Jiang, Bailing Xu, Lina Chen, Jie Xu
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 53-56.   doi:10.16039/j.cnki.cn22-1249.2018.07.012
    Abstract     PDF(491KB)
    Two imidazole inoic liquids containing biphenyl group [Cph-phC-Min]Br and [Cph-phC-Min-C]Br), were synthesized from 4,4'-biphenol, 1-bromododecane, 1,10-dibromodecane, N-methylimidazolium, and imidazole with microwave irradiation and the optimal conditions have been studied. The results showed that the yield of two products is 24.4% and 33.1% when N-alkyl imidazole and bromothane molar ratio 2:1 with microwave power is 80 W and reaction time 5 min, respectively. Compared with traditional methods, the reaction conditions in this study are easy to implement without inert gas protection, and the reaction time is shortened from 24 h to 5 min. The structure of ionic liquids containing biphenyl group was verified by IR and 1H NMR.
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    Synthesis and crystal structure of Cu(C10H14N4)(C7H4O3)2·3H2O: A coordination polymer with fish bone-like 1D chain   Collect
    QU Xiao-shu, SHI Dan, LI Yan, YANG Yan-yan
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 57-60.   doi:10.16039/j.cnki.cn22-1249.2018.07.013
    Abstract     PDF(924KB)
    A novel coordination polymer ofCu(C10H14N4)(C7H4O3)2·3H2O (1) (C10H14N4 = 1,1'-(1,4-butanediyl) bis (imidazole) (bbi); C7H4O3= p-hydroxybenzoic acid) has been synthesized by convenient aqueous solution method and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR spectra and TG analysis. Single-crystal X-ray analysis reveals that the title compound is crystallized in the monoclinic system, space group R-3c with a = 20.614(19)?, b = 12.349(11)?, c = 12.003(11)?, α = 90°, β = 116.840(14)°, γ = 90°, V = 2726(4)?3, Z = 4, F(000) = 1892, S = 1.054, R1 = 0.1044, wR2 = 0.2062 [I>2σ(I)].
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    The Quantitative Analysis of amaranth in candy by Using Graphene Quantum Dots as a Fluorescence-Quenching Probe   Collect
    JIN Li, WANG Ying, LIU Fang-tong, ZHANG Ke-shi, ZHANG Jian-po
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 61-65.   doi:10.16039/j.cnki.cn22-1249.2018.07.014
    Abstract     PDF(711KB)
    A fluorescence quenching method was used to quantitative analysis amaranth in candy based on the fluorescent quenching of graphene quantum dots. In order to obtain reliable results, effect of pH and reaction time on fluorescent quenching of graphene quantum dots by amaranth was studied. Under the optimized conditions, the fluorescence quenching of graphene quantum dots F0/F had a linear relationship with the concentration of amaranth between 0.5 - 3 μg/L. Temperature-dependent experiment, absorbance spectra and dynamic fluorescence quenching rate constant were used to discuss the quenching mechanism, all results indicated that it was a static quenching process based on the formation of complex between graphene quantum dots and amaranth through hydrogen bond. Particularly, this method was used to quantitative analysis candy sample, indicated that this method could be applied for practical food samples.
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    Study on the Effect of Ginsenoside and Polygala Saponins on the Treatment of Alzheimer's Disease in Rats   Collect
    LI Hui, ZHANG Yan
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 66-70.   doi:10.16039/j.cnki.cn22-1249.2018.07.015
    Abstract     PDF(616KB)
    The combined method of aluminum trichloride and D-galactose was used to establish Alzheimer's disease (AD) model in rats and to study the therapeutic effect of ginsenoside and Polygala saponins on AD rats. The effects of the compatibility of ginsenosides and Polygala saponins on spatial cognitive ability, memory acquisition and memory consolidation of AD rats were evaluated by Morris water maze experiment and passive avoidance platform experiment. The activity of acetylcholinesterase (AchE) in serum and brain tissue, and the effects of Panax ginsenoside and Polygala saponins on the activity of AchE in AD rats and the antioxidant capacity were evaluated by the level of malondialdehyde, catalase, total superoxide dismutase and glutathione peroxidase. The results showed that the compatibility of ginsenoside and Polygala saponins could effectively improve the spatial cognitive ability, memory acquisition and memory consolidation of AD model rats, and had the effect of treating AD. Its therapeutic effect on AD is related to reducing AchE activity and resisting oxidative damage caused by free radicals.
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    Prepareration of PMMA/SiO2 Hybrid Sol-Gel Materials in Optimization   Collect
    HAN Dan-dan, OU YANG Tian-wei, SHEN Ye, PAN Yi-fan, WANG Zhen
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 71-74.   doi:10.16039/j.cnki.cn22-1249.2018.07.016
    Abstract     PDF(357KB)
    Tetraethylorthosilicate (TEOS) was used as source material and hydrochloric acid or ammonia was used as catalyst to prepare PMMA/SiO2 hybrid sol-gel materials by free radical polymerization and in-situ sol-gel process. The mechanism and synthesis methods of sol-gel process were discussed. The factors such as hydrochloric acid, water and temperature on reaction rate and structure of the gel were reviewed which provide data for further research and practical application.
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    Preparation and Electrochromic Property of Vanadium Substituted Phosphotungstate/Congo Red Nanocomposite   Collect
    FENG Su-yang, ZHONG Jian-qiang, TAN Jia-ning, QU Xiao-shu, YANG Yan-yan
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 75-78.   doi:10.16039/j.cnki.cn22-1249.2018.07.017
    Abstract     PDF(1132KB)
    A electrochromic material based on vanadium substituted phosphotungstate (K7P2W16V2O62·18H2O)and congo red has been prepared by layer-by-layer (LbL) method, and characterized by UV-visible spectra, and cyclic voltammograms. It shows that the growth process of composite materials is uniform and stable. The composite film displays adjustable colors and undergoes transitions from red to maroon ,then to red, resulting in an optical contrast of 20.11 % and a coloration efficiency of 33 cm2 C-1. Furthermore, the switching times were 4.74 s for coloration, and 8.16 s for bleaching.
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    Preparation and Characterization of Monodisperse Magnetic Polymer Microspheres   Collect
    Qihui Shen, Beibei Liu, Yan Liu
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 79-81.   doi:10.16039/j.cnki.cn22-1249.2018.07.018
    Abstract     PDF(890KB)
    Fe3O4 particles, which were reduced by hydrazine hydrate with narrow size distribution, as the magnetic carriers, monodisperse and superparamagnetic polystyrene magnetic microspheres were prepared by dispersion polymerization. The morphology, structure and superparamagnetic properties of the microspheres were characterized. The results showed that magic polymer microspheres have good superparamagnetic and smooth surface. This method was suitable for the preparation of monodisperse particles with diameter about 1 μm. The magnetic polymer microspheres were capable of efficient magnetic targeting.
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    Preparation of the functional magnetic diatomite and its application in Congo red adsorption   Collect
    LIAN Li-li, LV Jin-yi, XIU Chao, Zhang Xin-yang, LOU Da-wei
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 82-85.   doi:10.16039/j.cnki.cn22-1249.2018.07.019
    Abstract     PDF(505KB)
    A functional magnetic diatomite material was prepared by modification the Fe3O4 and FeSiO3 on the surface. It was characterized by XRD and infrared spectroscopy. Then the magnetic adsorbent (Fe3O4@D@FeSiO3) was used to adsorb Congo red from aqueous solutions. The ability of magnetic diatomite has been carried out as function of contact time, temperature, pH and concentration. The results indicated that the functional magnetic diatomite was simple in synthesis, low in cost. The functional magnetic diatomite is characterized of simple preparation, low-cost raw materiel, convenient magnetic separation, and exhibited excellent uptake capacity for Congo red.
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    Hydrothermal Synthesis and crystal structure of Cu12Cl2(trz)8[HPMo12O40]]n   Collect
    YU Xiao-yang, LUO Ya-nan, QU Xiao-shu, YANG Yan-yan, REN Hong, JIN Li
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 86-89.   doi:10.16039/j.cnki.cn22-1249.2018.07.020
    Abstract     PDF(1879KB)
    A new polyoxometalates compound, Cu12Cl2(trz)8[HPMo12O40]]n (1)(trz = 1,2,4-1H-triazole), has been synthesized under hydrothermal condition and characterized by elemental analysis, IR and single crystal X-ray diffraction. It crystallizes in the monolinic system, space group C2/m, a = 2.1618(4) nm, b = 2.16726(10) nm, c = 1.60124(15) nm, β = 117.090(11)°, V = 6.3207(14) nm3, Z = 4. In addition, the fluorescence property of compound 1 was also investigated.
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    The Preliminary Purification of Polysaccharide from Rubus crategefolius Bunge. Root and Their Antioxidant Activity in vitro   Collect
    YANG Xiu-dong, ZHANG Pin-mei, ZHANG Yan, ZHANG Yang, CUI Hao, ZHOU Hong-li
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 90-94.   doi:10.16039/j.cnki.cn22-1249.2018.07.021
    Abstract     PDF(453KB)
    The crude polysaccharide of Rubus crategefolius Bunge. root was extract using water-extract and ethanol-precipitation method. It was further purified through de-protein and dialysis as well as DEAE-52 cellulose column chromatography. Two purified polysaccharide, RCP-1 and RCP-2 were obtained. The in vitro antioxidant activity of RCP-1 and RCP-2 was determined by DPPH, superoxide anion and ABTS scavenging assays. The results showed that the polysaccharide content of RCP-1 and RCP-2 were 80.66% and 82.15%, repectively. RCP-1 and PCP-2 had scavenging effect on DPPH, ABTS and superoxide anion. It also showed the concentration-dependent relationship. RCP-2 showed higher antioxidant activity that RCP-1. The results indicated that polysaccharide from Rubus crategefolius Bunge. root have a good antioxidant activity. It might be the material basis of the bioactivity of water soluble component of Rubus crategefolius Bunge. root.
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    Synthesis of Porous biomass carbon/NiCo2S4 Composite for High Performance Supercapacitors   Collect
    XU Xing-xing, YU Di, WANG Hao, HAN Ming-xuan, JIANG Li-li
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 95-99.   doi:10.16039/j.cnki.cn22-1249.2018.07.022
    Abstract     PDF(3910KB)
    In this work, Metaplexis japonica was used as raw material to prepare porous biomass carbon (AMJ) using KOH as activator. A facile two-step method is developed for growth of NiCo2S4 nanoparticles on AMJ, involving the growth of Ni-Co precursor by hydrothermal approach and subsequent conversion into NiCo2S4 nanoparticles through sulfidation process. The microstructure and morphologies of the resulting materials were characterized by XRD, SEM and N2 adsorption desorption analysis. The specific surface area of porous biomass carbon materials with tubular structure was 2831 m2/g, which was beneficial to charge accumulation between the electrolyte/electrode interfaces, and promote the diffusion and transport of electrolyte ions. Compared with pure NiCo2S4, the AMJ/NiCo2S4 electrode exhibited high specific capacitance of 1041.6 F/g at 5 mV/s, excellent rate capability and outstanding cycling stability.
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    Theoretical Study on Isomerization Process of Simple Ketone’s Molecules   Collect
    YANG Xue, ZHANG Yue, DENG Peng
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 100-105.   doi:10.16039/j.cnki.cn22-1249.2018.07.023
    Abstract     PDF(921KB)
    The isomerization processes of acetone and butanone molecules were studied by B3LYP and QCISD (T), and the reasonable reaction channels were obtained. The possible intermediates and products were analyzed, and the mechanism of isomerization reaction of simple ketone molecules was summarized. The information obtained is helpful to analyze the experimental results and provide theoretical basis and reference for further research.
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    Design of Remote Early Warning System for Production Environment   Collect
    Chen Lei, Wang Wei
    Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 106-110.   doi:10.16039/j.cnki.cn22-1249.2018.07.024
    Abstract     PDF(881KB)
    This design is based on STC89C52RC MCU as the wireless production environment monitoring system, which consists of detection terminal and monitoring terminal. The detection terminal realizes the collection of environmental parameters such as temperature and humidity in production environment, light intensity collection, smoke and other environmental parameters, and the wireless transmission of collection information can be realized through the nRF24L01 wireless transceiver module. The monitoring terminal can receive the data sent by the detection terminal and display the parameter information and warning alarm in real time. If there is alarm information, it will be sent directly to the mobile phone terminal of the staff via TC35i in order  to minimize the economic loss of industrial production and protect personal safety, which has practical application value.
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