Small particle ZSM-5 Zeolite were synthesized by hydrothermal method with different surfactants such as SDBS, PEG and Tween. The effects of different surfactants and synthesis conditions on the synthesis of small particle ZSM-5 zeolite were studied. The physical properties of the products were characterized by means of X-ray diffraction(XRD),Scanning electron microscopy(SEM). When adding 2.5g Tween surfactant , the dispersion and particle size reached the best level.