Integration of socialist core values into modernization of national governance acts as a significant way of cultivating and practicing core values and is also the internal requirement for modernization of national governance. Socialist core values act as the value guidance and ideological guarantee of modernization of national governance, which in turn provides core values with institutional support. With so many problems and challenges, it is an important subject to deeply explore an effective path to combine new-era socialist core values and modernization of national governance, so as to improve and develop socialist system with Chinese characteristics and realize the Chinese Dream of the great rejuvenation of the Chinese nation.