Cu12Cl2(trz)8[HPMo12O40]]n的水热合成与结构表征

doi:10.16039/j.cnki.cn22-1249.2018.07.020

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摘要利用水热技术合成了一种多酸化合物Cu₁₂Cl₂(trz)₈[HPMo₁₂O₄₀]]_n （1）（trz = 1,2,4-三氮唑），通过元素分析、红外和X-射线单晶衍射对其结构进行了表征。1为单斜晶系，C2/m空间群，a = 2.1618(4) nm, b = 2.16726(10) nm, c = 1.60124(15) nm, β = 117.090(11)°, V = 6.3207(14) nm3, Z = 4。同时也对其进行了荧光性质的测试。

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	于晓洋
	罗亚楠
	曲小姝
	杨艳艳
	任红
	金丽

关键词: 多酸 1,2,4-三氮唑晶体结构

Abstract: A new polyoxometalates compound, Cu₁₂Cl₂(trz)₈[HPMo₁₂O₄₀]]_n （1）（trz = 1,2,4-1H-triazole）, has been synthesized under hydrothermal condition and characterized by elemental analysis, IR and single crystal X-ray diffraction. It crystallizes in the monolinic system, space group C2/m, a = 2.1618(4) nm, b = 2.16726(10) nm, c = 1.60124(15) nm, β = 117.090(11)°, V = 6.3207(14) nm3, Z = 4. In addition, the fluorescence property of compound 1 was also investigated.

Key words: polyoxometalate 1,2,4-1H-triazole crystal structure

出版日期: 2018-07-25 发布日期: 2018-07-25 整期出版日期: 2018-07-25

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引用本文:

于晓洋, 罗亚楠, 曲小姝, 杨艳艳, 任红, 金丽. Cu₁₂Cl₂(trz)₈[HPMo₁₂O₄₀]]_n的水热合成与结构表征[J]. 吉林化工学院学报, 2018, 35(7): 86-89.
YU Xiao-yang, LUO Ya-nan, QU Xiao-shu, YANG Yan-yan, REN Hong, JIN Li. Hydrothermal Synthesis and crystal structure of Cu₁₂Cl₂(trz)₈[HPMo₁₂O₄₀]]_n. Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 86-89.

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https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2018.07.020 或 https://xuebao.jlict.edu.cn/CN/Y2018/V35/I7/86

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