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吉林化工学院学报, 2025, 42(3): 1-6     https://doi.org/10.16039/j.cnki.cn22-1249.2025.03.001
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一步电沉积法制备316不锈钢表面疏水涂层
许钊伟,王珊*
吉林化工学院 材料科学与工程学院,吉林吉林132022
One-Step Electrodeposition Method for Preparing Hydrophobic Coatings on The Surface of 316 Stainless Steel
XU Zhao-wei,WANG Shan*
School of Material Science & Engineering,Jilin Institute of Chemical Technology,Jilin City 132022,China
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摘要 316不锈钢是工业中广泛使用的结构材料,长期暴露在潮湿的服役环境中,其腐蚀是不容忽视的主要问题。在本文中,我们提出了一种简便的一步电沉积方法可实现在316不锈钢表面制备牢固的六水硝酸铈/肉豆蔻酸复合材料疏水涂层,该涂层具有优异的疏水性能,可有效地降低316不锈钢的腐蚀电位。通过改变电沉积时间和电压,优化了复合疏水涂层的疏水性能。采用水接触角测量、扫描电子显微镜(SEM)、傅里叶红外光谱(FTIR)和X射线衍射仪(XRD)对涂层的疏水性及结构进行了相应的表征。结果表明,利用该一步电沉积方法制得的316不锈钢表面疏水涂层静态水接触角最大可达到141.50±1.2°。电化学实验表明,电沉积复合疏水涂层的样品其抗电化学腐蚀能力与316不锈钢相比明显增强。
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许钊伟
王珊
关键词:  316不锈钢    电沉积    疏水涂层    
Abstract: 316 stainless steel is a widely used structural material in industrial applications, and its corrosion remains a critical issue when exposed to humid environments over prolonged periods. In this study, we developed a facile one-step electrodeposition method to fabricate a robust cerium nitrate hexahydrate/myristic acid composite hydrophobic coating on 316 stainless steel. The coating exhibits excellent hydrophobicity and effectively lowers the corrosion potential of the substrate. By optimizing the electrodeposition time and voltage, the hydrophobic performance and structural stability of the composite coating were significantly improved. The hydrophobicity and microstructure of the coating were systematically characterized using water contact angle measurements, scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). Results show that the static water contact angle of the optimized hydrophobic coating reaches 141.5 ± 1.2°. Electrochemical tests demonstrate that the coated sample exhibits significantly enhanced electrochemical corrosion resistance compared to bare 316 stainless steel, with a notable decrease in corrosion current density and positive shift in corrosion potential.
Key words:  316 stainless steel      electrodeposition      hydrophobic coating.
               出版日期:  2025-03-25      发布日期:  2025-12-20      整期出版日期:  2025-03-25
ZTFLH:  0614.23  
引用本文:    
许钊伟, 王珊. 一步电沉积法制备316不锈钢表面疏水涂层[J]. 吉林化工学院学报, 2025, 42(3): 1-6.
XU Zhao-wei, WANG Shan. One-Step Electrodeposition Method for Preparing Hydrophobic Coatings on The Surface of 316 Stainless Steel. Journal of Jilin Institute of Chemical Technology, 2025, 42(3): 1-6.
链接本文:  
https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2025.03.001  或          https://xuebao.jlict.edu.cn/CN/Y2025/V42/I3/1
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