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吉林化工学院学报, 2025, 42(3): 38-43     https://doi.org/10.16039/j.cnki.cn22-1249.2025.03.006
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碳纳米管增强陶瓷基复合材料的高温抗氧化性能研究
孙燕 ,牛莉,张新建
安徽机电职业技术学院  机械工程学院,安徽芜湖 241002
High Temperature Oxidation Resistance of Carbon Nanotubes Reinforced Ceramic Matrix Composites
SUN Yan, NIU Li, ZHANG  Xinjian
School of Mechanical Engineering, Anhui Mechanical and Electrical Vocational and Technical College, Wuhu  241002,China
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摘要 

为研究复合材料的分散性能、高温稳定性及相变行为问题,研究碳纳米管增强陶瓷基复合材料的高温抗氧化性能采用酸性液体处理碳纳米管,使用处理后的碳纳米管结合氧化铝陶瓷基材料制备出粉末材料,通过烧结将该粉末制备成碳纳米管增强陶瓷基复合材料块体。分析不同纳米管用量下该复合材料的氧化质量增长值以及热失重率,通过微观分析确定烧结温度与烧蚀距离变化下,该复合材料的高温抗氧化性能。试验结果显示,碳纳米管用量为35 %时,该复合材料的氧化质量增长值以及热失重率均较低,高温抗氧化性能较好;烧结温度为1500 ℃时,复合材料内部较为紧密,不易出现氧化;烧蚀距离较近时,会导致该材料高温抗氧化性能被破坏,因此需要注意该材料的使用环境。

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孙燕
牛莉
张新建
关键词:  碳纳米管    抗氧化    烧结温度    氧化铝    陶瓷基    热失重率    
Abstract:  To study the dispersion performance, high-temperature stability and phase transformation behavior of composite materials, the high-temperature oxidation resistance of carbon nanotube-reinforced ceramic matrix composites is investigated. Carbon nanotubes were treated with acidic liquid. The treated carbon nanotubes were combined with alumina ceramic matrix materials to prepare powder materials, and the powder was sintered to form carbon nanotube-reinforced ceramic matrix composite material blocks. The increase in oxidation mass and the thermogravimetric loss rate of the composite material under different amounts of carbon nanotubes were analyzed. The high-temperature oxidation resistance of the composite material under the changes of sintering temperature and ablation distance was determined through microscopic analysis. The test results show that when the dosage of carbon nanotubes is 35%, the increase value of oxidation mass and the thermogravimetric loss rate of the composite material are both relatively low, and the high-temperature oxidation resistance performance is good. When the sintering temperature is 1500 ℃, the interior of the composite material is relatively compact and oxidation is not likely to occur. When the ablation distance is relatively close, it will lead to the destruction of the high-temperature oxidation resistance of this material. Therefore, attention should be paid to the usage environment of this material.
Key words:  carbon nanotubes      anti-oxidation      sintering temperature      alumina      ceramic base      thermogravimetric ratio
               出版日期:  2025-03-25      发布日期:  2025-12-20      整期出版日期:  2025-03-25
ZTFLH:  TB333  
引用本文:    
孙燕, 牛莉, 张新建. 碳纳米管增强陶瓷基复合材料的高温抗氧化性能研究[J]. 吉林化工学院学报, 2025, 42(3): 38-43.
SUN Yan, NIU Li, ZHANG Xinjian. High Temperature Oxidation Resistance of Carbon Nanotubes Reinforced Ceramic Matrix Composites. Journal of Jilin Institute of Chemical Technology, 2025, 42(3): 38-43.
链接本文:  
https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2025.03.006  或          https://xuebao.jlict.edu.cn/CN/Y2025/V42/I3/38
[1] 李茂东, 欧阳文璟, 陈志刚, 任凯. 石墨烯基复合材料的吸波性能研究 [J]. 吉林化工学院学报, 2018, 35(9): 98-103.
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