过渡金属催化C-H活化插羰反应研究进展

doi:10.16039/j.cnki.cn22-1249.2019.03.001

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摘要

卤代芳烃的插羰反应是合成含羰基化合物的有效途径，使用未被官能化的C-H键实现插羰反应，具有更重要的价值。近年来，过渡金属催化C-H活化的偶联反应备受关注，但C-H键断裂需要很高的能量，对底物的结构和催化剂的类型要求苛刻。本文从反应中使用催化剂类型的角度，综述了过渡金属催化C-H键插羰反应的研究进展。

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	谢宁
	金朝辉
	高华晶
	孙健

关键词: 过渡金属 C-H活化插羰偶联反应

Abstract:

The carbonylative coupling reactions of aryl halides are effective way to synthesize carbonyl compounds. There are more valuable to realize the carbonylative coupling by C-H unactivation. In recent years, transition metal-catalyzed carbonylative coupling reactions have attracted more attention. But more energy will be needed in the cleavage process of C-H and the demands of the structure of substrates and types of catalyst are very harsh. We summarize the advances in transition metal-catalyzed carbonylative coupling by C-H bond activation from the point of the types of catalyst.

Key words: transition metal C-H activation carbonylative coupling

出版日期: 2019-03-25 发布日期: 2019-03-25 整期出版日期: 2019-03-25

O621.3

引用本文:

谢宁, 金朝辉, 高华晶, 孙健. 过渡金属催化C-H活化插羰反应研究进展 [J]. 吉林化工学院学报, 2019, 36(3): 1-8.
XIE Ning, JIN Zhaohui, GAO Huajing, SUN Jian. Advances in Transition Metal-Catalyzed Carbonylative Coupling by C-H Bond Activation . Journal of Jilin Institute of Chemical Technology, 2019, 36(3): 1-8.

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https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2019.03.001 或 https://xuebao.jlict.edu.cn/CN/Y2019/V36/I3/1

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