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吉林化工学院学报, 2025, 42(5): 48-53     https://doi.org/10.16039/j.cnki.cn22-1249.2025.05.008
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基于电催化氧化技术的水处理工程有机污染物降解
高慧慧1  魏娜娣2
1安徽水利水电职业技术学院 市政与交通工程学院,安徽 合肥  231603;
2河北师范大学汇华学院 工学部,河北 石家庄  050091
Degradation of organic pollutants in water treatment engineering based on electrocatalytic oxidation technology
Gao Huihui  Weinadi
School of Municipal and Transportation Engineering, Anhui Water Resources and Hydropower Vocational and Technical College, Hefei, Anhui 231603) 
Engineering Department, Huihua College of Hebei Normal University, Shijiazhuang Hebei 050091, China
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摘要 在实际的水处理过程中,高能耗一直是制约电催化氧化技术在水处理工程中应用的主要限制因素。为了降低电催化氧化技术在处理水中有机污染物方面的能耗,研究通过电弧喷涂技术引入氮化锆中间层,并采用电沉积法提升钛基PbO2阳极的稳定性和使用寿命。结果表明,通过添加氮化锆中间层,PbO2的晶体颗粒得到了显著的细化,颗粒分布更加均匀,且晶体结构更加致密。这种结构上的优化显著提高了电极表面对电解液侵蚀的抵抗力,从而增强了电极的稳定性和耐用性。对含4-氨基-7氯喹啉污水的处理结果表明,在中性条件下,经过3小时、电流密度为20 mA/cm2的电解处理,可以达到95.85%的污染物去除率。此次研究能够有效处理水处理工程中的有机污染物,对化工污水等含有复杂污染物的水体提供了有效的解决方案。
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关键词:  电催化氧化  水处理工程  有机污染物  降解  电弧喷涂    
Abstract: In the actual water treatment process, high energy consumption has always been the main limiting factor restricting the application of electrocatalytic oxidation technology in water treatment engineering. In order to reduce the energy consumption of electrocatalytic oxidation technology in treating organic pollutants in water, zirconium nitride intermediate layer was introduced by arc spraying technology, and the stability and service life of titanium-based PbO2 anode were improved by electrodeposition. The results show that by adding zirconium nitride intermediate layer, the crystal particles of PbO2 are significantly refined, the particle distribution is more uniform, and the crystal structure is more dense. This structural optimization significantly improves the resistance of the electrode surface to electrolyte erosion, thus enhancing the stability and durability of the electrode. The results of the treatment of wastewater containing 4-amino-7 chloroqualine showed that the removal rate of pollutants could reach 95.85% after electrolytic treatment with current density of 20mA/cm2 for 3 hours under neutral conditions. This research can effectively treat organic pollutants in water treatment engineering, and provide effective solutions for water bodies containing complex pollutants such as chemical wastewater.

Key words:   Electrocatalytic oxidation      Water treatment works      Organic pollutants      Degradation      Arc spraying
               出版日期:  2025-05-25      发布日期:  2025-12-20      整期出版日期:  2025-05-25
ZTFLH:  TQ630.7   
引用本文:    
高慧慧, 魏娜娣. 基于电催化氧化技术的水处理工程有机污染物降解[J]. 吉林化工学院学报, 2025, 42(5): 48-53.
Gao Huihui Weinadi. Degradation of organic pollutants in water treatment engineering based on electrocatalytic oxidation technology. Journal of Jilin Institute of Chemical Technology, 2025, 42(5): 48-53.
链接本文:  
https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2025.05.008  或          https://xuebao.jlict.edu.cn/CN/Y2025/V42/I5/48
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