鱼骨状一维链结构配位聚合物Cu(C10H14N4)(C7H4O3)2·3H2O的合成与晶体结构

doi:10.16039/j.cnki.cn22-1249.2018.07.013

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摘要采用常规水溶液法合成了一个结构新颖的配位聚合物Cu(C₁₀H₁₄N₄)(C₇H₄O₃)₂·3H₂O(1) (C₁₀H₁₄N₄ = 1,1'-(1,4-丁基)双咪唑(bbi); C₇H₄O₃ = 对羟基苯甲酸)，用X-射线单晶衍射、红外光谱、元素分析和X射线粉末衍射对晶体结构进行了表征。该晶体属于单斜晶系，R-3c空间群，a = 20.614(19)?，b=12.349(11)?，c=12.003(11)?，α=90°，β= 116.840(14)°，γ= 90°，V = 2726(4)?3，Z=4, F(000)=1892, S=1.054，R1=0.1044，wR2=0.2062 [I>2σ(I)]。

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	曲小姝
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	李岩
	杨艳艳

关键词: 合成配位聚合物晶体结构

Abstract: A novel coordination polymer ofCu(C₁₀H₁₄N₄)(C₇H₄O₃)₂·3H₂O (1) (C₁₀H₁₄N₄ = 1,1'-(1,4-butanediyl) bis (imidazole) (bbi); C₇H₄O₃= p-hydroxybenzoic acid) has been synthesized by convenient aqueous solution method and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR spectra and TG analysis. Single-crystal X-ray analysis reveals that the title compound is crystallized in the monoclinic system, space group R-3c with a = 20.614(19)?, b = 12.349(11)?, c = 12.003(11)?, α = 90°, β = 116.840(14)°, γ = 90°, V = 2726(4)?3, Z = 4, F(000) = 1892, S = 1.054, R1 = 0.1044, wR2 = 0.2062 [I>2σ(I)].

出版日期: 2018-07-25 发布日期: 2018-07-25 整期出版日期: 2018-07-25

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引用本文:

曲小姝, 石丹, 李岩, 杨艳艳. 鱼骨状一维链结构配位聚合物Cu(C₁₀H₁₄N₄)(C₇H₄O₃)₂·3H₂O的合成与晶体结构[J]. 吉林化工学院学报, 2018, 35(7): 57-60.
QU Xiao-shu, SHI Dan, LI Yan, YANG Yan-yan. Synthesis and crystal structure of Cu(C₁₀H₁₄N₄)(C₇H₄O₃)₂·3H₂O: A coordination polymer with fish bone-like 1D chain. Journal of Jilin Institute of Chemical Technology, 2018, 35(7): 57-60.

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https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2018.07.013 或 https://xuebao.jlict.edu.cn/CN/Y2018/V35/I7/57

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