邻香兰素乙醇溶液比色法检测Fe3+
王雪1 ,魏文琦1 ,张铁华2
1.吉林化工学院 材料科学与工程学院;2.吉林毓文中学
Colorimetric Detection of Fe3+ by using O-Vanillin in Ethanol Solution
WANG Xue, WEI Wenqi, ZHANG Tiehua
摘要
人体中铁元素含量过多会引起人体组织损坏、皮肤色素沉着、肝脾功能性障碍等病状。研究利用Fe3+ 与邻香兰素乙醇溶液反应生成藏蓝色络合物的特性,实现了对溶液中Fe3+ 的快速检测。邻香兰素乙醇溶液对Fe3+有较强的选择性。在Fe3+ 浓度为0~200 μM的范围内,不同浓度的Fe3+ 的紫外光的吸收大小与Fe3+ 浓度呈良好的线性关系(R=0.99299),邻香兰素乙醇溶液对Fe3+ 的检测限约为1 μM。
关键词:
邻香兰素
比色法
Fe3+
络合反应
Abstract:
Excessive iron content in human body can cause human tissue damage, skin pigmentation, liver and spleen dysfunction and other symptoms. In this paper, the reaction of Fe3+ with o-vanillin ethanol solution to form the dark blue complex was studied. O-vanillin ethanol solution has strong selectivity to Fe3+ . In the range of Fe3+ concentration 0~200 μM , the ultraviolet light absorption of Fe3+ with different concentrations showed a good linear relationship with Fe3+ concentration (R=0.99299), the detection limit of o-vanillin ethanol solution on Fe3+ was about 1 M.
Key words:
o-vanillin
colorimetry
Fe3+
complexation reaction
出版日期: 2019-05-25
发布日期: 2019-05-25
整期出版日期: 2019-05-25
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