主链引入含氟基团对双酚A型聚芳醚酮材料性能影响的研究

doi:10.16039/j.cnki.cn22-1249.2019.05.017

下载:

PDF (876KB)
输出: BibTeX | EndNote (RIS)

摘要

利用亲核缩聚的方法分别合成主链含有甲基的双酚A型聚芳醚酮和含有三氟甲基的双酚A型聚芳醚酮，通过溶胶-凝胶法得到了透明的聚合物薄膜。通过1H-NMR确定了两种聚芳醚酮的结构。通过DSC研究发现，主链含有甲基的聚芳醚酮的Tg为159oC，主链含有三氟甲基的聚芳醚酮的Tg为166oC，两种聚合物5%热失重温度均在460oC以上，都表现出良好的热稳定性。通过接触角研究发现，主链含有甲基的聚芳醚酮的水接触角为78o，主链含有三氟甲基的聚芳醚酮的水接触角为91o，表现出更加优异的疏水性能。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	（）
	作者相关文章
	王永鹏
	霍昕彤
	王洪涛
	张清元
	刘梦竹

关键词: 含氟基团双酚A型聚芳醚酮疏水性能

Abstract:

In this paper, bisphenol-a poly(aryl ether ketone)s containing methyl and trifluoromethyl were synthesized respectively, and transparent polymer films were obtained by the sol-gel method. The structures of two poly(aryl ether ketone)s were determined by 1H-NMR. DSC study showed that the Tg of the bisphenol-a poly(aryl ether ketone)s with main chain containing methyl (BPA-PAEKs) was 159oC, and that the Tg of poly(aryl ether ketone)s with main chain containing trifluoromethyl (6FBPA-PAEKs) was 166oC, and the 5% weight loss of both polymers was more than 460oC, showing good thermal stability. Through the study on the contact Angle, it was found that the water contact Angle of the BPA-PAEKs was 78o, and that the water contact Angle of the 6FBPA-PAEKs was 91^o, the latter shows better hydrophobic performance.

Key words: fluorine group bisphenol A polyavyl ether ketone composites ormance ')" href="#">hydrophobic performance

出版日期: 2019-05-25 发布日期: 2019-05-25 整期出版日期: 2019-05-25

O648.17

引用本文:

王永鹏, 霍昕彤, 王洪涛, 张清元, 刘梦竹. 主链引入含氟基团对双酚A型聚芳醚酮材料性能影响的研究 [J]. 吉林化工学院学报, 2019, 36(5): 70-74.
WANG Yongpeng, HUO Xintong, WANG Hongtao, ZHANG Qingyuan, LIU Mengzhu. Study on the Effect of Fluorine-Containing Groups on the Properties of Bisphenol A Polyavyl Ether Ketone Composites . Journal of Jilin Institute of Chemical Technology, 2019, 36(5): 70-74.

链接本文:

https://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2019.05.017 或 https://xuebao.jlict.edu.cn/CN/Y2019/V36/I5/70

[1]	WANG Ya-hong, JIA Ying-chao. Optimization for Soxhlet Extraction of Total Flavonoids from Eggplant Root by Using Response Surface Methodology[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 1 -6 .
[2]	PAN Hong-wei, ZHOU Hong-li. Research Progress on Extraction Technology and Component Analysis of Volatile Flavor Compounds in Plants[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 7 -10 .
[3]	SUN Xiao-feng, YU Wen-xin, ZHU Ming-wei, JIE Meng, JIANG De-lon. Research on the Piezoelectric Pump Application in Continuous Ink Supply System of the Inkjet Printer[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 15 -18 .
[4]	HAN Jie, WANG Kai-bao, ZHOU Zhen-qiang, LIU Yu-li, SONG Chun-lei, QIN Qing-kun. Design and Modal Analysis of Ozone Disinfection Cleaning Machine for Fruits and Vegetables[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 27 -30 .
[5]	ZHOU Zhen-qiang, WANG Kai-bao, CHEN Yu-tian, HAN Ji, HOU Dai-bing, GUO Wen-qi. Analysis of the Design and Dynamic Characteristics of Recyclable Garbage Crushing Device[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 31 -35 .
[6]	ZHU Qi-rui, ZHANG Yu-feng, LI Yang-xin, WU Dong-jun, BI Shuai-nan, ZHOU Rui-jie, YOU Sai-sai. The Structural Design and Parameter Analysis of the Chair Structure of Quadriplegia of Cerebral Palsy[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 40 -44 .
[7]	JIANG Di, QIN Ti-zhi, HAN Ming-xuan, ZHANG Zhi-hui, ZHANG Yu. Catalytic Performance of Sulfonic Acid Resins on the Transalkylation of Dinonylphenol with Phenol[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 48 -51 .
[8]	ZHANG Yun-peng. Preparation and Characterization of Er³⁺，Y³⁺，Yb³⁺ Co-doped Al₂O₃ Luminescence Materials[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 58 -63 .
[9]	MI Ya-wei. Proof of the Manifold of n Manifold[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 64 -66 .
[10]	XU You-zhuan, ZHOU Hou-qing. The Lower Bounds of Energy for Some Circulant Graph[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 67 -72 .