Please wait a minute...
吉林化工学院学报, 2019, 36(5): 64-69     https://doi.org/10.16039/j.cnki.cn22-1249.2019.05.016
  本期目录 | 过刊浏览 | 高级检索 |
聚丙烯酸超吸水凝胶的制备及其吸水性与耐盐性研究
刘梦竹,相昌荣,王鑫,路大勇,王永鹏
吉林化工学院 材料科学与工程学院
Preparation of Polyacrylic Acid Hydragel and Research of its Water Absorbency&Salt-tolerance
LIU Mengzhu, XIANG Changrong, WANG Xin, LU Dayong, WANG Yongpeng
下载:  PDF (496KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 

利用水溶液聚合法合成一种成本低廉的聚丙烯酸超吸水凝胶(SAP)并测试其吸水性及耐盐性。结果表明,该树脂在水及盐溶液中均具有较高的吸水率,分别为220 g/g和36g/g。60℃高温保水性实验表明,该树脂在高温下可持续保水720分钟以上。重复吸放五次后,吸附量仍可分别达到第一次吸附量的95.55%和90.12%,循环吸附性能良好。吸水能力较强,是树脂中亲水性基团与网格内渗透压共同作用的结果。离子的存在是吸水倍率下降的主要原因,但仍表现出高吸水性质,表明聚丙烯酸树脂具有一定耐盐性。对该树脂在水及盐溶液中的吸附动力学和扩散动力学的研究表明,吸附动力学均属于伪二阶动力学模型,即过程为自发、放热过程。扩散动力学机理表明,聚丙烯酸在水中符合 non-Fickian 扩散,是具有较快吸附速率的主要原因;在0.9wt%NaCl溶液中符合Fickian 扩散,即金属离子向聚合物中的扩散起主导作用。这种具有高吸水性能、良好保水性能的水凝胶有望作为保水剂应用于农业,园林等领域。

服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
刘梦竹
相昌荣
王鑫
路大勇
王永鹏
关键词:  聚丙烯酸  超吸水凝胶  耐盐性  吸水性  动力学     
Abstract: 

A low cost polyacrylate superabsorbent hydrogel (SAP) was synthesized by aqueous solution polymerization. Its absorbency and salt-tolerance were studied subsequently. The results showed that the resin had a high water absorption rate of 220 g/g and 36g/gin water and salt solution, respectively. Then the hydrogel was suffered 60 ℃ high temperature to characterize the water retention. It showed that the resin have the ability to sustain water more than 720 minutes at high temperature. After repeated adsorption and discharge for five times, the adsorption amount can still reach 95.55% and 90.12% of the first adsorption amount respectively, demonstrating a good recycling adsorption performance. The high water absorbency was due to the synergistic effect of hydrophilic groups in the resin and osmotic pressure in the mesh. The presence of ions is the main reason for the decrease of water absorption ratio, but it still showed a high water absorption property, indicating that polyacrylic resin has a certain salt tolerance. The adsorption kinetics and diffusion kinetics of the resin in water and salt solution were studied. The diffusion kinetics showed that the polyacrylic acid in water was non-fickian diffusion, which was the main reason for the fast adsorption rate. Fickian diffusion was consistent in 0.9wt%NaCl solution, that is, metal ions played a leading role in the diffusion of polymer. The hydrogels with high water absorption and good water retention properties are expected to be used as water retention agents in agriculture, gardens and other fields.

Key words:  polyacrylic acid    superabsorbent hydrogel    salt-tolerance    water absorbency    adsorption kinetics
               出版日期:  2019-05-25      发布日期:  2019-05-25      整期出版日期:  2019-05-25
ZTFLH:  O648.17  
引用本文:    
刘梦竹, 相昌荣, 王鑫, 路大勇, 王永鹏. 聚丙烯酸超吸水凝胶的制备及其吸水性与耐盐性研究 [J]. 吉林化工学院学报, 2019, 36(5): 64-69.
LIU Mengzhu, XIANG Changrong, WANG Xin, LU Dayong, WANG Yongpeng. Preparation of Polyacrylic Acid Hydragel and Research of its Water Absorbency&Salt-tolerance . Journal of Jilin Institute of Chemical Technology, 2019, 36(5): 64-69.
链接本文:  
http://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2019.05.016  或          http://xuebao.jlict.edu.cn/CN/Y2019/V36/I5/64
[1] 陈海伦, 田爱华. 基于Fluent的液体进料DMFC阳极两相流数值分析 [J]. 吉林化工学院学报, 2019, 36(1): 29-35.
[2] 王凯晨, 王淑坤. 基于CFD的汽车空调除霜性能分析及优化[J]. 吉林化工学院学报, 2018, 35(5): 72-76.
[3] 陈 丽, 付 强, 王桂英, 何 龙, 王洪艳, 孙纯国. 油页岩地下原位热解动力学研究[J]. 吉林化工学院学报, 2018, 35(1): 1-3.
[1] WANG Ya-hong, JIA Ying-chao. Optimization for Soxhlet Extraction of Total Flavonoids from Eggplant Root by Using Response Surface Methodology[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 1 -6 .
[2] PAN Hong-wei, ZHOU Hong-li. Research Progress on Extraction Technology and Component Analysis of Volatile Flavor Compounds in Plants[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 7 -10 .
[3] ZHOU Zhen-qiang, WANG Kai-bao, CHEN Yu-tian, HAN Ji, HOU Dai-bing, GUO Wen-qi. Analysis of the Design and Dynamic Characteristics of Recyclable Garbage Crushing Device[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 31 -35 .
[4] ZHU Qi-rui, ZHANG Yu-feng, LI Yang-xin, WU Dong-jun, BI Shuai-nan, ZHOU Rui-jie, YOU Sai-sai. The Structural Design and Parameter Analysis of the Chair Structure of Quadriplegia of Cerebral Palsy[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 40 -44 .
[5] ZHANG Yun-peng. Preparation and Characterization of Er3+Y3+Yb3+ Co-doped Al2O3 Luminescence Materials[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 58 -63 .
[6] MI Ya-wei. Proof of the Manifold of n Manifold[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 64 -66 .
[7] XU You-zhuan, ZHOU Hou-qing. The Lower Bounds of Energy for Some Circulant Graph[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(3): 67 -72 .
[8] ZHOU Hong-li, ZHANG Yang, CUI Hao, XUE Jian-fei. Primary Exploration of the Applied Pharmaceutical Talents Training in Ordinary Engineering Colleges Based on Social Needs and R ecruitment Drives[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(2): 1 -4 .
[9] YANG Xiu-dong, WANG Ya-hong, ZHANG Pin-mei, YANG Yan-jun, CUI Hao, ZHOU Hong-li. Discussion on the Practice Teaching Reform of Pharmaceutical Engineering Based on Engineering Education Professional Accreditation[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(2): 5 -7 .
[10] LI Long, WANG Xue-mei. Research on Higher Education Assessment Mode Based on Formative Evaluation and Information Entropy Theory[J]. Journal of Jilin Institute of Chemical Technology, 2018, 35(2): 8 -12 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed