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吉林化工学院学报, 2023, 40(5): 1-4     https://doi.org/10.16039/j.cnki.cn22-1249.2023.05.001
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碳负载镍铁合金电催化剂的合成及其析氧反应活性研究
张洁1**,张鹏1**,付牙林1**,张瑞君2,王嘉博1*,张吉波1*
1.吉林化工学院 石油化工学院,吉林 吉林 132022 2.中国石油吉林石化公司 乙烯厂,吉林 吉林 132022
Synthesis and Electrocatalytic Oxygen Evolution Activity of Carbon Supported NiFe Alloy Electrocatalysts
ZHANG Jie1**, ZHANG Peng1**, FU Yalin1**, Zhang Ruijun2, WANG Jiabo1*, ZHANG Jibo1*
1.School of Petrochemical Engineering , Jilin Institute of Chemical Technology, Jilin 132022, China) 2. Ethvlene Plant of Jilin Petrochemical Company , PetroChina, Jilin 132022, China
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摘要 

采用简单的一步煅烧法制备了碳负载NiFe双金属催化剂。并通过XRD、SEM和TEM对样品的物相、结构和形貌进行研究分析,成功制备了碳负载镍铁合金电催化剂。进一步探究不同的NiFe金属比例对电解水析氧反应性能的影响。其中Ni2Fe@NC的析氧反应(OER)活性最为显著,达到10mA·cm-2的电流密度时,过电位为330mV,Tafel斜率为58.9 mV·dec-1。并且我们对Ni2Fe@NC的稳定性进行了研究,采用计时电流法对Ni2Fe@NC催化剂进行10000s的持续测试,证明其具备优异的稳定性。

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张洁
张鹏
付牙林
张瑞君
王嘉博
张吉波
关键词:  二氰二胺  葡萄糖  双金属  析氧反应     
Abstract: 

Carbon supported NiFe bimetallic catalyst were prepared by a simple one-step calcination process. And the phase, structure, and morphology of the sample were studied and analyzed through XRD, SEM, and TEM, and a carbon supported nickel iron alloy electrocatalyst was successfully prepared. The effect of different NiFe metal ratios on the oxygen evolution reaction performance of Electrolysed water was further investigated. The oxygen evolution reaction activity of Ni2Fe@NC was the most significant. When the current density of 10mA·cm-2 is reached, the overpotential was 330mV, the Tafel slope was 58.9 mV·dec-1. In addition, we studied the stability of Ni2Fe@NC and tested Ni2Fe@NC catalyst for 10000s continuously by using chronoamperometry, demonstrating its excellent stability.

Key words:  Dicyandiamine    Glucose    Bimetal    oxygen evolution reaction
               出版日期:  2023-05-25      发布日期:  2023-05-25      整期出版日期:  2023-05-25
ZTFLH:  O 646  
引用本文:    
张洁, 张鹏, 付牙林, 张瑞君, 王嘉博, 张吉波. 碳负载镍铁合金电催化剂的合成及其析氧反应活性研究 [J]. 吉林化工学院学报, 2023, 40(5): 1-4.
ZHANG Jie, ZHANG Peng, FU Yalin, Zhang Ruijun, WANG Jiabo, ZHANG Jibo. Synthesis and Electrocatalytic Oxygen Evolution Activity of Carbon Supported NiFe Alloy Electrocatalysts . Journal of Jilin Institute of Chemical Technology, 2023, 40(5): 1-4.
链接本文:  
http://xuebao.jlict.edu.cn/CN/10.16039/j.cnki.cn22-1249.2023.05.001  或          http://xuebao.jlict.edu.cn/CN/Y2023/V40/I5/1
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